Optoelectronic devices built from graphene could be much simpler in design than those made from other materials. If a method for efficiently depositing layers of graphene — a major area of research in materials science — can be found, it could ultimately lead to optoelectronic chips that are simpler and cheaper to manufacture.
“Another advantage, besides the possibility of making device fabrication simpler, is that the high mobility and ultrahigh carrier-saturation velocity of electrons in graphene makes for very fast detectors and modulators,” says Dirk Englund, the Jamieson Career Development Assistant Professor of Electrical Engineering and Computer Science at MIT, who led the new research.
In a new graphene-on-silicon photodetector, electrodes (gold) are deposited, slightly asymmetrically, on either side of a silicon waveguide (purple). The asymmetry causes electrons kicked free by incoming light to escape the layer of graphene (hexagons) as an electrical current.
Graphene is also responsive to a wider range of light frequencies than the materials typically used in photodetectors, so graphene-based optoelectronic chips could conceivably use a broader-band optical signal, enabling them to move data more efficiently. “A two-micron photon just flies straight through a germanium photodetector,” Englund says, “but it is absorbed and leads to measurable current — as we actually show in the paper — in graphene.”
As Englund explains, the problem with graphene as a photodetector has traditionally been its low responsivity: A sheet of graphene will convert only about 2 percent of the light passing through it into an electrical current. That’s actually quite high for a material only an atom thick, but it’s still too low to be useful.
When light strikes a photoelectric material like germanium or graphene, it kicks electrons orbiting atoms of the material into a higher energy state, where they’re free to flow in an electrical current. If they don’t immediately begin to move, however, they’ll usually drop back down into the lower energy state. So one standard trick for increasing a photodetector’s responsivity is to “bias” it — to apply a voltage across it that causes the electrons to flow before they lose energy.
The problem is that the voltage will inevitably induce a slight background current that adds “noise” to the detector’s readings, making them less reliable. So Englund, his student Ren-Jye Shiue, Columbia’s Xuetao Gan — who, together with Shiue, is lead author on the paper — and their collaborators instead used a photodetector design developed by Fengnian Xia and his colleagues at IBM, which produces a slight bias without the application of a voltage.
In the new design, light enters the detector through a silicon channel — a “waveguide” — etched into the surface of a chip. The layer of graphene is deposited on top of and perpendicular to the waveguide. On either side of the graphene layer is a gold electrode. But the electrodes’ placement is asymmetrical: One of them is closer to the waveguide than the other.
“There’s a mismatch between the energy of electrons in the metal contact and in graphene,” Englund says, “and this creates an electric field near the electrode.” When electrons are kicked up by photons in the waveguide, the electric field pulls them to the electrode, creating a current.
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